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KMID : 1059519930370090826
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Journal of the Korean Chemical Society
1993 Volume.37 No. 9 p.826 ~ p.831
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Substitution Reactions of Cyanopyridines with Organometallics
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Kim Jung-Gyun
Yu Dong-Sik
Moon Sung-Hwan
Park Jin-Il
Park Won-Woo
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Abstract
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3-Cyanopyridine, when treated with organolithium or Grignard reagents, gives addition to the 6-position and provides a series of 2-substituted 5-cyanopyridines (6-substituted 3-cyanopyridines). Alternatively, 2-and 4-cyanopyridine react with CH3Li or CH3MgI and provide 2-acetylpyridine and 4-acetylpyridine, respectively.
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